Knoevenagel反應
...在下縮合得到a,b-不飽和化合物。反應機理:反應實例:參考文獻:[1]DoebnerModification.EKnoevenagel,Ber.,1898,31,2596.[2]O.Doebner,Ber.,1900,33,2140.[3]J.R.JohnsoninOrganicReactions1,pp226,233(NewYork,1942).[4]L.F.FieserandM.Fieser,OrganicChemistry3rded,p692(NewYork,195...
化學Paal-Knorr反應
...應,可得吡咯、噻吩及其衍生物。反應機理:反應實例:參考文獻:[1]C.Paal,Ber.18,367(1885)[2]L.Knorr,Ber.18,299(1885)[3]H.FischerandH.Orth,DieChemiedewPyrrols1,p34(Leipzig,1934)[4]D.M.YoungandC.F.H.Allen,OrganicSyntheses16,25(1936)[5]A.H.CorwininElderfield,H...
化學Robinson縮環反應
...是Micheal加成反應,第二步是羥醛縮合反應。反應實例:參考文獻:[1]E.C.duFeu,F.J.McQuillinandR.Robinson,J.Chem.Soc.1937,53.[2]A.L.WildsandC.H.Shunk,J.Amer.Chem.Soc.65,469(1943)[3]A.L.WildsandR.G.Werth,J.Org.Chem.17,11491154(1952)[4]J.H.BrewsterandE.L.Eliel,OrganicReac...
化學Reformatsky反應
...有機鋅試劑與醛酮的羰基進行加成,再水解:反應實例:參考文獻:[1]S.Reformatskii,Ber.,1887,20,1210;J.Russ.Phys.Chem.Soc.,1890,22,44.[2]R.L.Shriner,OrganicReactionsI,NewYork,1942,pI.[3]H.E.ZimmermanandM.D.Traxler,J.Amer.Chem.Soc.,1957,79,1920.[4]L.H.Klemm,G.M.Bauer,J.Org.Ch...
化學Schiemann反應
...子,受到氟硼酸根負離子進攻後得到氟代苯。反應實例:參考文獻:[1]G.BalzandG.Schiemann,Ber.,1927,60,1186.[2]H.S.Boothetal.,J.Amer.Chem.Soc.,193557,2064.[3]D.T.Flood,OrganicSynthesescoll.cod.,11,295.[4]G.SchiemannandW.Winkelmuller,ibid.,1943,299.[5]A.Roe,OrganicReactionsV,1...
化學Sandmeyer反應
...HCl或HBr來實現(Gattermann反應)。反應機理:反應實例:參考文獻:[1]T.Sandmeyer,Ber.,1884,17,1633,2650.[2]L.Gattermann,Ber.,1890,23,1218.[3]S.C.Dickerman,K.WeissandA.K.Ingberman,J.Org.Chem.,1956,21,308.[4]H.H.Hodgson,Chem.Rev.,1947,40,251.[6]S.C.Dickerman,K.WeissandA.K.Ingberm...
化學Stephen還原
...水氯化亞錫的乙醚懸浮液還原,水解生成醛:反應實例:參考文獻:[1]H.Stephen,J.Chem.Soc.,127,1874(1925)[2]Williams,J.Amer.Chem.Soc.,61,2248(1939)[3]Ferguson,Chem.Revs.38,243(1946)[4]MosettiginOrganicReactionsvol.8,246(1954)[5]BayerinHouben-Weyl,MethodenderOr...
化學Strecker氨基酸合成法
...是製備a-氨基酸的一個簡便方法。反應機理:反應實例:參考文獻:[1]A.Strecker,Ann.,1850,75,27;1854,91,349.[2]D.T.Mowry,Chem.Rev.,1948,42,236.[3]Th.Wielandetal.,inHouben-Weyl-Müller,1958,11,305.[4]E.Erlenmeyer,S.C.Passavant,Ann.,1800,200,120.[5]G.Stadnikoff,Ber.,1907,40,1014...
化學Wittig-Horner反應
...Wittig反應類似,加成後的消除步驟略有差別。反應實例:參考文獻:[1]L.Horneretal.,Chem.Ber.,1958,91,61.[2]J.Bautagy,R,Thomas,Chem.Rev.,1974,74,87.[3]W.S.Wadsworth,W.D.Emmons,J.Amer.Chem.Soc.,1961,[4]L.Horner,W.Klink,H.Hoffmann,Chem.Ber.,1963,96,3133.參見:Wittig反應
化學Wagner-Meerwein重排
...會發生重排反應,得到重排產物:反應機理:反應實例:參考文獻:[1]G.Wagner,J.Russ.Phys.Chem.Soc.31,690(1899)[2]H.Meerwein,Ann.405,129(1914)[3]H.Meerweinetal.,Amid417,255(1918);435,174(1923);453,16(1927);Ber.53,1815(1920);55,2500(1922);J.Prakt.Ch...
化學