Dakin反應
...羥基芳醛或芳酮都能發生此反應。反應機理:反應實例:參考文獻:[1]H.D.Darkin,Amer.Chem.,1909,42,4177.[2]R.Criegee,Ann.,1948,560,127.[3]S.L.Friess,J.Amer.Chem.Soc.,1949,71,2571.[4]Y.S.Agasimundin,S.Siddappa,J.Chem.Soc.,PerkinTrans.,1973,I,503.
化學Demjanov重排
...烷醇也能發生類似的重排反應,詳見Tiffeneau-Demjanov重排。參考文獻:[1]N.J.DemjanovandM.Lushnikov,J.Russ.Phys.Chem.Soc.,35,26(1903)[2]Chem.Zentr.,1903,I,828.[3]N.J.Demjanov,J.Russ.Phys.Chem.Soc.,36,186(1904)[4]Chem.Zentr.,1904,I,1214;Ber.,40,4393,4961(1907)[5]N.J.De...
化學Elbs反應
...率不高。反應機理:本反應的機理尚不清楚。反應實例:參考文獻:[1]K.ElbsandE.Larsen,Ber.,17,2847(1884)[2]K.Elbs,J.Prakt.Chem.,12,33,180(1836);35,465(1887);41,1,121(1890)[3]E.Clar,Ber.,62,3S0,IS74(1929);L.F.Fieser,OrganicReactions,I,129(NewYork,1942)...
化學Eschweiler-Clarke反應
...甲醛在這裏作爲一個甲基化試劑。反應機理:反應實例:參考文獻:[1]W.Eschweiler,Ber.,38,880(1905)[2]H.T.Clarke,H.B.Gillespie,andS.Z.Weisshaus,J.Amer.Chem.Soc.,55,4571(1933)[3]Moore,OrganicReactions,5,301(1949)[4]F.Moller,R.Schroter,MethodenderOrganischenChemie,X...
化學Favorskii反應
...、二甲苯等均能作爲反應的溶劑。反應機理:反應實例:參考文獻:[1]A.Favorskii,J.Russ.Phys.Chem.Soc.,1905,37,643;Chem.Zentr.,1905,II,1018.[2]A.Babayan,B.Akopyan,R.Gyuli-Kevhyan,J.Gen.Chem(U.S.S.R.),9,1631(1939);C.A.1940,34,2788.[3]A.W.Johnson,TheChemistryofAcetyleni...
化學Bucherer反應
...再進一步互變異構爲酮(Ⅲ)或亞胺(Ⅳ)。反應實例:參考文獻:[1]H.T.Bucherer,J.Prakt.Chem.,1904,69(2),49.[2]H.T.Bucherer,J.Prakt.Chem.,1904,70(2),345.[3]H.T.Bucherer,J.Prakt.Chem.,1907,75(2),249.[4]H.T.Bucherer,J.Prakt.Chem.,1905,75(2),433.[5]N.L.Drake,Or...
化學Favorskii重排
...法可用於合成張力較大的四員環。反應機理:反應實例:參考文獻:[1]A.E.Favorskii,J.Ptakt.Chem.,[2]88,658(1913)[2]A.E.FavorskiiandV.N.Bozhovskii,J.Russ.Phys.Chem.Soc.,46,1097(1914)[3]C.A.9,1900(1915);O.Wallach,Ann.,414,296(1918)[4]J.G.AstonandR.B.Greenburg,J....
化學Fries重排
...成鄰位異構產物(熱力學控制)。反應機理:反應實例:參考文獻:[1]K.FriesandG.Fink,Ber.,41,4271(1908)[2]K.FriesandW.Pfaffendorf,ibid.,43,212(1910)[3]Blatt,Chem.Reus.,27,413(1940)[4]BlattinOrganicReactionsvol.1,342(NewYork,1942)[5]Thomas,AnhydrousAluminumChl...
化學Friedel-Crafts酰基化反應
...,在酰基化中不發生烴基的重排。反應機理:反應實例:參考文獻:[1]Y.Yamase,Bull.Chem.Soc.,Japan,1961,34,480.[2]R.Corriu,Bull.Soc.Chim.,France,1965,821.[3]S.E.Rasmussen,N.C.Broch,ActaChem.Scand.,1966,20,1351.[4]W.R.EdwardJr.,E.C.Sibelle,J.Org.Chem.,1963,28,674.[5]F.Uhlig,H....
化學Gattermann-Koch反應
...亞銅)存在下反應,生成芳香醛:反應機理:反應實例:參考文獻:[1]L.GattermannandJ.A.Koch,Ber.,1897,30,1622.[2]L.Gattermann,Ann.,1906,347,347.[3]N.N.CrounseinOrganicReactions,V,p290(NewYork,1949)[4]D.J.Cram,G.S.Hammond,OrganicChemistry,p382(NewYork,1959)[5]Dilke,El...
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